Add the coffee to 1/3 cup of boiling water and stir until it dissolves, then set this aside to cool while you prepare the other ingredients.
Add the vinegar and milk to another bowl, give it a stir then set aside.
Preheat your oven to 350 degrees Fahrenheit (180 degrees Celsius).
Grease a 6" round baking tin, and line it with parchment paper.
Sift the flour, cocoa, sugar, baking soda, baking powder and salt together in a bowl. Then use a whisk to stir it and make sure everything is evenly combined. Set this bowl aside.
In a second bowl combine the oil, egg, vanilla extract and milk using an electric mixer on medium speed.
Add the dry ingredients to the wet ingredients and use your electric mixer for about a minute to combine it all together. Then add the coffee and mix again for a few seconds until everything is all mixed in and the batter is smooth. The batter will be runny.
Pour your batter into the prepared baking tin and bake it in the oven until just cooked through. This will take about 25-28 minutes, but check regularly (refer to my blog above for advice about how to tell if your cake is cooked just right).
Once the cake is cooked, remove it from the oven and allow it to cool for 10 minutes in the cake tin. Then gently flip the cake tin over a plate so the cake falls out. Remove the parchment paper from the cake and gently transfer it to a wire rack to cool completely.
Once the cake is cool cover it in plastic wrap until you plan to decorate it (this will lock in the moisture). The cake can be stored in the fridge for up to 2 days, or in the freezer for up to 3 months.If you plan to freeze the undecorated cake, wrap it in an extra layer of plastic wrap and then a layer of tin foil (this will help avoid freezer burn).